You might want to check with Matt Murphy of Hobby Bunker, if you want to cast the object out of expanding foam. If I'm not mistaken, HB's line of buildings is cast from a expaning resin foam, which gives a light-weight but strong casting.
I think Ken from All the King's Men also uses foam buildings, you might want to check with him.
Both are members of the forum, too, so I'd send them a couple of PMs.
Personally, I've never used an expanding foam for casting, only metal.
Prost!
Brad